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Thermochromism in an Organic Crystal Based on the Coexistence of σ- and π-Dimers

 



 

Thermochromism in an Organic Crystal Based on the Co-existence of σ- and π-Dimers
MORITA Yasushi and SUZUKI Shuichi (Graduate School of Science)


Introduction

Figure 1


Temperature dependent X-ray crystal structure analyses

Figure 2


Temperature dependent UV-vis spectra

Figure 3


Thermochromic mechanism
 
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Magnetic properties in the crystalline state
Energy diagram in the crystalline state
Conclusion

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